Table.ColumnNames

Table.ColumnNames(
    Table.FromRecords({
        [CustomerID = 1, Name = "Bob", Phone = "123-4567"],
        [CustomerID = 2, Name = "Jim", Phone = "987-6543"],
        [CustomerID = 3, Name = "Paul", Phone = "543-7890"],
        [CustomerID = 4, Name = "Ringo", Phone = "232-1550"]
    })
)

{"CustomerID", "Name", "Phone"}